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Liquid Crystals and their Application
Russian Journal

Zhidkie kristally i ikh prakticheskoe ispol'zovanie

Жидкие кристаллы и их практическое использование

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Zhidk. krist. ikh prakt. ispol'z. = Liq. Cryst. and their Appl., 2020, 20 (1), 6—18.
DOI: 10.18083/LCAppl.2020.1.6





Synthesis of Organotriphenylphosphonium Halides, Quaternary Ammonium Salts and Study of their Application as Surfactants Soluble in Liquid Crystals



N. M. Kuz'menok1, S. G. Mikhalyonok1, А. S. Arol1, M. O. Shevchuk1, V. S. Bezborodov1,@, M. N. Krakhalev2,3, V. S. Sutormin2,3, O. O. Prishchepa2,3, G. M. Zharkova4, V. Ya. Zyryanov2

Author affiliations
1Belarusian State Technological University,
13-a Sverdlova St., Minsk, 220006, Belarus
E-mail: v_bezborodov@yahoo.com
2Kirensky Institute of Physics, Federal Research Center KSC SB RAS,
50 Akademgorodok, Krasnoyarsk, 660036, Russia
2Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk, 660041, Russia
4Khristianovich Institute of Theoretical and Applied Mechanics, SB RAS,
4/1 Institutskaya St., Novosibirsk, 630090, Russia

Abstract
Quaternary ammonium salts and organotriphenylphosphonium halides have been synthesized. Their ions can have an orienting effect on liquid crystals. The solubility of the obtained compounds in the nematic liquid crystal – 4-cyano-4'-pentylbiphenyl (5CB) has been studied. It was shown that two ammonium salts both dissolve in the nematic and also dissociate into ions. At that, the anions moving in electric field can modify the boundary conditions. This fact allows using these compounds for the ion-surfactant method of controlling liquid crystal materials.

Keywords: liquid crystal, nematic, surfactant, quaternary ammonium salt, organotriphenylphosphonium halides, ionic-surfactant method





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