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Liquid Crystals and their Application Russian Journal Zhidkie kristally i ikh prakticheskoe ispol'zovanie Жидкие кристаллы и их практическое использование |
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Zhidk. krist. ikh prakt. ispol'z. = Liq. Cryst. and their Appl., 2020, 20 (1), 6—18. DOI: 10.18083/LCAppl.2020.1.6 |
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Synthesis of Organotriphenylphosphonium Halides, Quaternary Ammonium Salts and Study of their Application as Surfactants Soluble in Liquid Crystals
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N. M. Kuz'menok1, S. G. Mikhalyonok1, А. S. Arol1, M. O. Shevchuk1, V. S. Bezborodov1,@,
M. N. Krakhalev2,3, V. S. Sutormin2,3, O. O. Prishchepa2,3, G. M. Zharkova4, V. Ya. Zyryanov2
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Author affiliations 1Belarusian State Technological University,
13-a Sverdlova St., Minsk, 220006, Belarus E-mail: v_bezborodov@yahoo.com
2Kirensky Institute of Physics, Federal Research Center KSC SB RAS,
50 Akademgorodok, Krasnoyarsk, 660036, Russia
2Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk, 660041, Russia
4Khristianovich Institute of Theoretical and Applied Mechanics, SB RAS,
4/1 Institutskaya St., Novosibirsk, 630090, Russia
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Abstract Quaternary ammonium salts and organotriphenylphosphonium halides have been synthesized. Their ions can have an orienting effect on liquid crystals. The solubility of the obtained compounds in the nematic liquid crystal – 4-cyano-4'-pentylbiphenyl (5CB) has been studied. It was shown that two ammonium salts both dissolve in the nematic and also dissociate into ions. At that, the anions moving in electric field can modify the boundary conditions. This fact allows using these compounds for the ion-surfactant method of controlling liquid crystal materials.
Keywords: liquid crystal, nematic, surfactant, quaternary ammonium salt, organotriphenylphosphonium halides, ionic-surfactant method
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