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Zhidk. krist. ikh prakt. ispol'z. = Liq. Cryst. and their Appl., 2009, 1, 57—62.
Physicochemical and Chromatographic Behavior Of Cellulose Acetates in the Binary Organic Solvent Systems
О. V. Alekseeva, S. V. Blokhina, M. V. Ol'hovich, A. V. Sharapova
Author affiliations Institute of Solution Chemistry, Russian Academy of Sciences
Russia 153045 Ivanovo, Akademicheskaya Str., 1. Е-mail: firstname.lastname@example.org
Abstract Hydrodynamic and sorption behavior of a number of cellulose acetates in diluted non-aqueous solutions were studied by viscosimetry and reversed gas chromatography techniques, respectively. Effect of the chemical nature of low-molecular organic substances on swelling of the molecular coils of the said polymers as well as the coil-to-rigid-rod conformational tran-sition of the macromolecules was revealed. Thermodynamic compatibility of the polymers with non-aqueous solvents at infinite dilution was determined.
Keywords: cellulose esters, hydrodynamic and sorption characteristics