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Liquid Crystals and their Application Russian Journal Zhidkie kristally i ikh prakticheskoe ispol'zovanie Жидкие кристаллы и их практическое использование |
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Zhidk. krist. ikh prakt. ispol'z. = Liq. Cryst. and their Appl., 2010, 1, 44—54. |
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Structural Transition in Polymer Dispersed Liquid Crystals Prepared Under Magnetic Field
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A. M. Parshin1,2, V. G. Nazarov2, V. A. Gunyakov1,2, V. Ya. Zyryanov1,2,3, V. F. Shabanov1,2,3
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Author affiliations 1Kirensky Institute of Physics, Krasnoyarsk Scientific Centre, SB RAS
Krasnoyarsk 660036, Akademgorodok 50, Russia. E-mail: parshin@iph.krasn.ru
2Siberian Federal University, Krasnoyarsk 660041, 79 Svobodny prospect, Russia
3M. F. Reshetnev Siberian State Aerospace University
Krasnoyarsk, 660014, 31 Krasnoyarsky rabochy prospect, Russia
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Abstract The structural transition within the nematic liquid crystal droplets of 4-n-pentyl-4'-cyanobiphenyl (5CB) and 4-n-pentyl-4'-cyanophenyl-cyclohexane (5PCH]) encapsulated in polyvinylbutyral matrix under magnetic field is reviewed. The nematic 5CB droplets formed under magnetic field H* < 4 кOe as well as the 5PCN droplets formed under H* < 5 кOe possess the classical bipolar structure. If H* > 4 kOe, the uniform and radial structures are observed also in ensemble of the 5CB droplets. A tendency to align the bipolar axes along the field is revealed within the 5PCN droplets formed under H* > 5 kOe. The radial structures inside the 5PCN droplets are absent. The spontaneous cyclic transition between the bipolar director configuration and homogenous structure can occur within the droplets in the temperature ranges t = (24 ÷ 34)oС for 5CB as well as t = (32 ÷ 54) oС for 5PCN. Moreover the second variant of structural transition: bipolar configuration – radial one is discussed.
Keywords: polymer dispersed liquid crystal, nematic droplet, director configuration, magnetic field, structural transition
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