Mesomorphism of Cation Water–Soluble Meso-Substituted Tetraphenylporphyrines and Their Metal Complexes

Liquid Crystals and their Application
Russian Journal

Zhidkie kristally i ikh prakticheskoe ispol'zovanie

Жидкие кристаллы и их практическое использование

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Zhidk. krist. ikh prakt. ispol'z. = Liq. Cryst. and their Appl., 2010, 4, 5—11.

Mesomorphism of Cation Water–Soluble Meso-Substituted Tetraphenylporphyrines and Their Metal Complexes

N. A. Bragina¹, N. V. Novikov¹, K. A. Formirovsky¹, V. V. Bykova², G. A. Anan'eva², N. V. Usol'tseva²

Author affiliations
¹Lomonosov Moscow State Academy of Fine Chemical Technology Russia 119571 Moscow, Vernadskogo Ave, 86 ¹ ²Ivanovo State University, Nanomaterials Research Institute ¹ 153025 Ivanovo, Ermak Str., 39.
E-mail: nv_usoltseva@mail.ru

Abstract
The mesomorphic properties of cation water-soluble meso-substituted tetraphenylporphyrines and their metal complexes were studied. Out of 10 studied compounds, five compounds are mesomorphic in thermotropic state, six of them possess lyotropic mesomorphism in binary systems with water, chloroform and benzene.

Keywords: synthesis, mesomorphism, water soluble cation meso-substituted tetraphenylporphyrines, metal complexes

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